Researchers at the U.S. Department of Energy’s National Renewable Energy Laboratory (NREL) and the University of Toledo have found that perovskite solar cells should be subjected to a combination of stress tests simultaneously to best predict how they will function outdoors.
The team used a state-of-the-art p-i-n PSC stack (with PCE up to ~25.5%) to show that indoor accelerated stability tests can predict 6-month outdoor aging tests. Device degradation rates under illumination and at elevated temperatures are most instructive for understanding outdoor device reliability. The team also found that the indium tin oxide (ITO)/self-assembled monolayer (SAM)-based hole transport layer (HTL)/perovskite interface most strongly affects the device operation stability. Improving the ion-blocking properties of the SAM HTL increases averaged device operational stability at 50°C–85°C by a factor of ~2.8, reaching over 1000 h at 85°C and to near 8200 h at 50°C with a projected 20% degradation, which is among the best to date for high-efficiency p-i-n PSCs.
Solar cells must endure a set of harsh conditions—often with variable combinations of changing stress factors—to judge their stability, but most researchers conduct these tests indoors with a few fixed stressing conditions. While these tests provide some necessary insight, understanding which stressor applied during indoor tests provided predictive correlations with outdoor operation is critical.
“We must understand how well perovskite solar cells will perform outdoors, under real conditions, to move this technology closer to commercialization,” said Kai Zhu, a senior scientist in the Chemistry and Nanoscience Center at NREL. “That’s why we identified accelerated testing protocols that can be conducted in the laboratory to reveal how these cells would function after six months in operation outside.”
Outdoor conditions, such as humidity, heat, and even light, put stress on solar cells. As a result, the efficiency of solar cells declines and power production decreases over time. To reach the reliability targets for commercialization of perovskite technology, protocols must first be established so that improvements from different groups can be easily validated and compared.
Researchers tend to test the stability of perovskite solar cells by exposing them to light and low temperatures. However, a broad range of testing conditions exists, making it challenging to compare different studies and discern their relevance to achieving the reliability needed for commercialization.
The research team put perovskite solar cells through a battery of tests. During the test for operational stability, the cells retained more than 93% of their maximum efficiency after about 5,030 hours of continuous operation. The cells were subjected to thermal cycling, with temperatures repeatedly fluctuating between -40 and 85 degrees Celsius. After 1,000 cycles, the cells showed an average of about 5% degradation.
The tests addressed different stressors, such as light and heat, separately. However, in real-world conditions, these individual factors act simultaneously to affect solar cell performance. When combined, for example, light and heat significantly accelerate performance degradation or cause new problems that were otherwise absent or occurring at slower rates when testing separately.
The researchers concluded that high temperature and illumination is the most critical combination of stressors for understanding how well a perovskite solar cell will perform outdoors.
