Perovskite Solar - Page 18

Researchers from the University of Science and Technology of China and Hefei University of Technology have developed a proof-of-concept tandem solar cell tandem solar cell by using antimony selenide (Sb₂Se₃) for the bottom cell and a wide-bandgap organic-inorganic hybrid perovskite material for the top cell. The device reached a power conversion efficiency of more than 20%, which demonstrates that antimony selenide has a high potential for bottom-cell applications.

Antimony selenide (Sb₂Se₃) possesses a band gap of 1.05–1.2 eV and has been widely applied in single-junction solar cells. Based on its band gap, Sb₂Se₃ can also be used as the bottom cell absorber material in tandem solar cells. Sb₂Se₃-based solar cells also exhibit excellent stability with nontoxic compositional elements. In this recent work, the team demonstrated a perovskite/antimony selenide four-terminal tandem solar cell with a specially designed and fabricated transparent electrode for an optimized spectral response.

Last week, it was reported that the Japanese government estimates the need for electricity output to rise 35% to 50% by 2050 due to growing demand from semiconductor plants and data centers backing artificial intelligence (AI).  Now, Japan's industry ministry has said that it will launch a public-private group this month with the aim of commercializing perovskite solar cells, which are thin, light and bendable. The consortium will see 150 public and private entities, including local governments, working together to accelerate the adoption of flexible perovskite solar panels. 

Perovskite solar cells, which can be installed flexibly in various places, such as on walls, are believed to hold the key to Japan's push for renewable energy. As the first step, the consortium will set a target for perovskite cell capacity by 2040. Current projections point to 38.8 GW, with the possibility of exceeding the capacity of conventional solar panels (70 GW) in the next decade, reaching 84.2 GW in 2050.

The Korea Research Institute of Chemical Technology (KRICT) and Korean semiconductor equipment maker UniTest have announced the joint development of a large-area perovskite solar cell with 20.6% efficiency, which they define as a record-breaking achievement.

They reportedly received the world’s highest efficiency certification from Fraunhofer and will be listed on the U.S. National Renewable Energy Laboratory (NREL)’s solar cell efficiency chart.

Researchers from the University of Victoria, University of British Columbia and Henan University recently used a cadmium iodide doping technique to stabilize the blade coating process in the manufacturing of solar cells based on formamidinium lead iodide (FAPbI₃) perovskite. The team built a cell showing a considerable increase in efficiency compared to an identical device without cadmium doping.

FAPbI₃ is one of the most promising perovskite materials for solar cell applications, as it offers a narrow energy bandgap and remarkable stability. However, there are still challenges to overcome considering the FAPbI₃ polymorphism issue and its hypersensitivity to fabrication conditions. The scientists hypothesized that introducing a homovalent Pb-site additive would be beneficial, and one such alternative is cadmium.

Researchers at the University of Toledo have designed a four-terminal (4T) tandem solar cell with a top device that uses a perovskite absorber with a tunable wide-bandgap and a bottom cell based on a commercially established narrow-bandgap absorber technology made of cadmium telluride (CdTe).

Perovskite-cadmium telluride tandem solar cells are relatively unexplored compared to other tandems. While the efficiency potential of CdTe-based tandems is lower than CIGS-based tandems due to the higher bandgap of the CdTe bottom cell, the broader commercial success of CdTe solar cells makes them interesting to investigate for thin-film tandem applications.

It was reported that about a week ago, Kunshan GCL Optoelectronic Material launched the first phase of a photovoltaic energy storage equipment production project was launched, backed by a total investment of Yuan 570 million (over USD$80 million).

The project is undertaken by Kunshan High-Tech Group, which is responsible for the customized construction of a high standard factory area for the 1 GW production project of perovskite photovoltaic modules for enterprises. 

As part of the Investing in America agenda, the U.S. Department of Energy (DOE) recently announced a $71 million investment in research, development, and demonstration projects to grow the network of domestic manufacturers across the U.S. solar energy supply chain. 

The selected projects will address gaps in the domestic solar manufacturing capacity for supply chain including equipment, silicon ingots and wafers, and both silicon and thin-film solar cell manufacturing. The projects will also open new markets for solar technologies such as dual-use photovoltaic (PV) applications, including building-integrated PV and agrivoltaics. 

Small-molecule ionic liquids are frequently used as efficient bulk phase modifiers for perovskite materials. However, their inherent characteristics, such as high volatility and ion migration, pose challenges in addressing the stability issues associated with perovskite solar cells (PSCs). Recently, researchers at China's Northwestern Polytechnical University and CNPC Tubular Goods Research Institute designed improved poly ionic liquids (ILs) with multiple active sites as efficient additives for perovskite materials.

The team's recent work shows how additive engineering with a polymerized ionic liquid to the metal halide perovskite material can improve the solar cell's function, helping to pave the way for the adoption of perovskite solar cells.

Researchers from EPFL, CSEM and Empa have demonstrated a cell design combining additive and substrate engineering that yields consistently high power conversion efficiencies and discussed various design aspects that are important for reproducibility and performance. 

The team presented two key developments with a synergetic effect that boost the PCEs of tandem devices with front-side flat Si wafers—the use of 2,3,4,5,6-pentafluorobenzylphosphonic acid (pFBPA) in the perovskite precursor ink that suppresses recombination near the perovskite/C60 interface and the use of SiO₂ nanoparticles under the perovskite film that suppress the enhanced number of pinholes and shunts introduced by pFBPA, while also allowing reliable use of Me-4PACz as a hole transport layer. 

Researchers at China's Shanghai University of Electric Power have used dibenzoylmethane (DBM) as a precursor additive introduced in order to regulate the crystallization of CsPbI₂Br perovskite while passivating its associated defects. 

Inorganic CsPbI₂Br perovskite solar cells (PSCs) have attracted massive interest but the tendency towards unruly crystallization and poor film quality of inorganic CsPbI₂Br perovskites are major factors limiting their performance improvement. In their recent work, the scientists used DBM additive engineering for efficient and stable carbon-based CsPbI₂Br PSCs.