New approach could allow for rapid and low-cost production of perovskite solar cells

An international team of researchers from EPFL, North Carolina State University, Centre for Hybrid and Organic Solar Energy (CHOSE) at the University of Rome Tor Vergata and Uppsala University has demonstrated a technique for producing perovskite photovoltaic materials on an industrial scale, which could reduce the cost and improve the performance of mass-produced perovskite solar cells. The technique is low-cost, simple and energy-efficient.

'In the lab, researchers produce perovskite photovoltaic materials using a technique called spin coating, which creates a thin film of perovskite on a substrate ' but only on a small scale,' says Aram Amassian, co-corresponding author of a paper on the work and a professor of materials science and engineering at North Carolina State University.

'We're talking about sample substrates that are only one or two centimeters square. However, people didn't think it was possible to scale spin-coating up for manufacturing, using substrates that are tens of centimeters square. Instead, people have opted for a variety of other methods. But these other methods produce perovskite photovoltaics that don't perform as well as the thin films made using spin coating and required significant research and development.'

'What we've done here is demonstrate that you can produce perovskite photovoltaics on larger substrates using spin coating by designing a co-solvent dilution strategy,' says Michael Grätzel, co-corresponding author of the paper and a professor at École Polytechnique Fédérale de Lausanne. 'In other words, you can scale up production of photovoltaics and preserve the excellent performance of almost any type of perovskite thin film produced using spin coating.'

Historically, people thought spin coating could not be used to produce perovskite photovoltaics on industrial-scale substrates in a material-efficient way because of the nature of both spin coating and perovskites.

Spin coating involves placing a liquid on the surface of a substrate and then spinning the substrate, so that the liquid material spreads across the surface. However, when perovskite is applied using this technique, the solvents that keep the perovskite in a liquid state don't evaporate quickly enough. This causes much of the perovskite to fly off the edges, meaning a lot of the perovskite material is wasted. It also results in irregular thickness of the perovskite on the surface, as well as some areas of the perovskite taking longer than others to dry. All of which is problematic from a manufacturing standpoint.

'Our approach tackles this challenge by introducing a co-solvent that allows the liquid perovskite to spread evenly and dry very quickly and uniformly,' says Hong Zhang of École Polytechnique Fédérale de Lausanne, who is a co-lead author on the paper.

The new technique also significantly reduces waste and, by extension, reduces toxic byproducts associated with manufacturing perovskite photovoltaics.

'The beauty of this technique is that many industries already use spin coating technologies to produce all sorts of products,' says Aldo Di Carlo, co-corresponding author of the paper and a professor at the University of Rome Tor Vergata. 'Our work demonstrates that these existing technologies could be used to create perovskite solar cells. This could really accelerate the production and deployment of perovskite solar panels and cells.'

Collaborators on the demonstration project are already using the new technique to produce modules that are tens of centimeters across with excellent uniformity and performance.

'My team is now focused on using process automation and artificial intelligence to build on this work and further improve efficiency, stability and sustainability of perovskite photovoltaics,' Amassian says. 'We're hoping to work with public and private sector interests on finding ways to implement this work and accelerate the development of perovskite solar cell technologies.'