Researchers develop method for fabrication of perovskite solar cells in ambient air

Existing fabrication processes for creating efficient metal halide perovskite solar cells (PSCs) require an inert (i.e., chemically inactive) atmosphere, such as that within a nitrogen glovebox. Recently, researchers from China's North China Electric Power University have introduced a strategy to create PSCs with PCEs above 25% in ambient air. 

This strategy is hoped to accelerate commercialization of PSCs. "The fabrication of perovskite solar cells (PSCs) in ambient air can accelerate their industrialization," Luyao Yan, Hao Huang and their colleagues wrote in their paper. "However, moisture induces severe decomposition of the perovskite layer, limiting the device efficiency. We show that sites near vacancy defects absorb water molecules and trigger the hydration of the perovskite, eventually leading to the degradation of the material." To fabricate their solar cells in ambient air conditions, the scientists blocked the pathway through which perovskite layers can become hydrated and consequently suffer severe damage. They did this using the acetate salt form of the chemical compound guanabenz, known as GBA.

"Guanabenz acetate salt eliminates both cation and anion vacancies, blocking the perovskite hydration and allowing the crystallization of a high-quality film in ambient air," the researchers wrote in their paper. "With guanabenz acetate salt, we prepare PSCs in ambient air with a certified efficiency of 25.08%."

In initial tests, the fabrication strategy proposed by this team of researchers appeared to yield excellent results, enabling the successful creation of stable solar cells based on metal halide perovskites exhibiting commercially viable PCEs above 25%. Remarkably, these solar cells also appeared to retain their performance over time, even after operating in humid environments.

"The PSCs without encapsulation maintain around 96% of their initial efficiency after 2,000 hours of aging in ambient air and after 500 hours of operating at the maximum power point under simulated air mass (AM) 1.5 G solar light in a N₂ atmosphere," Yan, Huang and their colleagues wrote. "The encapsulated devices retained 85% of their initial efficiency after 300 hours under damp heat conditions (85°C and 85% relative humidity)."