Researchers develop more stable 2D thermochromic perovskite for smart windows in building applications
Researchers from City University of Hong Kong have introduced a novel and durable 2D thermochromic perovskite, Tha2MAPbI4 (TMPI, Tha = thiourea, MA = methylamine), wherein Tha acts as a Lewis acid-base adduct. TMPI demonstrates a reversible transition, achieving 83.7% luminous transmittance in the cold state and 35.2% in the hot state, thereby showcasing a substantial solar modulation ability of 24.7%.
The background for this development is that despite growing interest in thermochromic metal halide perovskite (MHPs) for smart window applications, existing MHP smart windows predominantly feature 3D perovskite, which exhibits a deficiency in environmental stability, presenting persistent challenges for practical applications.