Researchers from ARC Centre of Excellence in Exciton Science, Monash University, University of Sydney and CSIRO Manufacturing have shown how water could be the 'secret ingredient' in a simple way to create perovskite crystals.
Ordinarily, water is kept as far away as possible during the process of creating perovskites as the presence of moisture is severely harmful to them. That’s why perovskites for scientific research are often made via spin coating in the sealed environment of a nitrogen glove box. However, in their new work, the researchers have found a simple way to control the growth of phase-pure perovskite crystals by harnessing water as a positive factor. This liquid-based mechanism works at room temperature, so the approach remains cost effective.
The team found that by changing the ratio of water to solvent during the early stages of the process, they could choose to grow different types of perovskite crystals, with structures to suit various purposes.
Corresponding author Dr Wenxin Mao of the Department of Chemical and Biological Engineering said: “By carefully tuning the concentration of water in the precursor solution, we realized the precise control of particular perovskite phases.”
Computational and thermodynamic analysis conducted by colleagues at the University of Sydney identified that the coordination of lead and bromide ions in the precursor solution was an important factor in determining which types of crystals are formed.
Lead author Qingdong Lin, a PhD student in the Department of Chemical and Biological Engineering, said: “We now understand the internal mechanics and function of water inside the precursor solution. By doing that we can further use water to control the crystallization process.”
To demonstrate the quality of the end product, crystals produced via this approach were coupled with back-contact electrodes through nanofabrication to create X-ray detection devices.
This test sample reportedly performed at a similar level to commercial X-ray detectors currently being used in real-world settings, like medical imaging and Geiger counters, and out-performed prototype perovskite X-ray detectors developed using slower, more complicated fabrication methods.
Wenxin said: “We compared them with commercial X-ray detectors as well as other types of perovskites and we do have a very good responsivity and sensitivity to X-rays. Overall this project shows that we have found a smart way to control inorganic perovskite single crystals. The methodology is flexible and feasible and doesn’t require a very unique environment or technique to apply it.”
As well as solar cells, X-ray detectors and LEDs, perovskites created with this method could also be useful in UV light detection, lasers and solar concentrators.
